Web10 jun. 2024 · A Pd-catalyzed carboxamide-directed enantioselective 1,2-carboboration reaction of unactivated alkenes with C – H nucleophiles and B 2 Pin 2 has been … Web9 nov. 2016 · Catalytic, Regioselective Hydrocarbofunctionalization of Unactivated Alkenes with Diverse C-H Nucleophiles J Am Chem Soc . 2016 Nov 9;138(44):14705 …
Publications – Molecular Complexity through Catalysis
WebA catalytic system comprised of a cobalt-diphosphine complex and a Lewis acid (LA) such as AlMe3 has been found to promote hydrocarbofunctionalization reactions of alkynes with Lewis basic and electron-deficient substrates such as formamides, pyridones, pyridines, and azole derivatives through site-selective C-H activation. Web14 mrt. 2024 · A Pd-catalyzed amide-directed enantioselective hydrocarbofunctionalization of unactivated alkenes with C-H nucleophiles has been … siddhinath sundram
Catalytic, Regioselective …
Web21 jun. 2024 · Alkene hydrocarbofunctionalization represents one of the most important classes of chemical transformations, but related branched-selective examples with unactivated olefins are scarce. Here, we report that catalytic amounts of a dimeric Ni(I) ... WebDeveloped in the Engle lab, this 2-pyridyl-8-aminoquinoline (PAQ) auxiliary is a pincer-like, removable tridentate directing group that stabilizes 6-membered palladacycles for olefin functionalization. Together with similar ligand PPA ( 901251 ), researchers demonstrated regioselective remote hydrocarbofunctionalization of alkene-containing ... Web3 jul. 2024 · C (sp 3 )-H functionalizations of light hydrocarbons using decatungstate photocatalysis in flow. C (sp. 3. )-H functionalizations of light hydrocarbons using decatungstate photocatalysis in flow. Science. 2024 Jul 3;369 (6499):92-96. doi: 10.1126/science.abb4688. the pills and razor